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DOI

By the method of helium thermal desorption from submicrocrystalline palladium presaturated in the gaseous phase, the diffusion coefficient Dff and solubility coefficient Ceff of helium are measured in the range P = 0-3 MPa and T = 293-508 K. The pressure dependence of Ceff flattens at high pressures. At low saturation pressures, the temperature dependences of the diffusion and solubility coefficients may be divided into (1) high-temperature (400-508 K) and (2) low-temperature (293-400 K) ranges described by the exponentials D1, 2 = D0exp(-E1,2D/kT) and C1, 2 = C0exp(-E1,2S/kT). The energies of diffusion activation are E2D = 0.0036 ± 0.0015 eV and E1D = 0.33 ± 0.03 eV, and the solution energies are E2S = -0.025 ± 0.008 eV and E1S = 0.086 ± 0.008 eV in the low- and high-temperature ranges, respectively. Mechanisms behind the diffusion and solution of helium are discussed. © 2002 MAIK "Nauka/Interperiodica".
Язык оригиналаАнглийский
Страницы (с-по)1440-1443
Число страниц4
ЖурналTechnical Physics
Том47
Номер выпуска11
DOI
СостояниеОпубликовано - 2002

    Предметные области WoS

  • Физика, Прикладная

    Предметные области ASJC Scopus

  • Физика и астрономия в целом

ID: 43957264