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DOI

The molecular-statics method and the Gourary-Adrian approach are used to calculate the displacements of the lattice ions nearest to the F center in alkali halide crystals with NaCl and CsCl structures (altogether, twenty crystals). The calculations are performed for the 1s and 2p states of the F-center electron with allowance for the angular dependence of the Coulomb potential created by the electron in the 2p state. The absorption and emission energies of the F center are calculated. The calculated energies agree qualitatively with experiment and reproduce the experimentally found tendencies of changes in these energies when going from one crystal to another.
Язык оригиналаАнглийский
Страницы (с-по)453-459
ЖурналPhysics of the Solid State
Том48
Номер выпуска3
DOI
СостояниеОпубликовано - 2006

    Предметные области WoS

  • Физика, Конденсированных сред

    Предметные области ASJC Scopus

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

ID: 42310059