The molecular-statics method and the Gourary-Adrian approach are used to calculate the displacements of the lattice ions nearest to the F center in alkali halide crystals with NaCl and CsCl structures (altogether, twenty crystals). The calculations are performed for the 1s and 2p states of the F-center electron with allowance for the angular dependence of the Coulomb potential created by the electron in the 2p state. The absorption and emission energies of the F center are calculated. The calculated energies agree qualitatively with experiment and reproduce the experimentally found tendencies of changes in these energies when going from one crystal to another.
Original languageEnglish
Pages (from-to)453-459
JournalPhysics of the Solid State
Volume48
Issue number3
DOIs
Publication statusPublished - 2006

    WoS ResearchAreas Categories

  • Physics, Condensed Matter

    ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

ID: 42310059