Standard

Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water. / Kizhnyaev, V. N.; Gorkovenko, O. P.; Safronov, A. P. и др.
в: Vysokomolekulyarnye soedineniya Seriya A & Seriya B, Том 39, № 3, 03.1997, стр. 527-532.

Результаты исследований: Вклад в журнал › Статья › Рецензирование

Harvard

Kizhnyaev, VN, Gorkovenko, OP, Safronov, AP & Adamova, LV 1997, 'Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water', Vysokomolekulyarnye soedineniya Seriya A & Seriya B, Том. 39, № 3, стр. 527-532.

APA

Kizhnyaev, V. N., Gorkovenko, O. P., Safronov, A. P., & Adamova, L. V. (1997). Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water. Vysokomolekulyarnye soedineniya Seriya A & Seriya B, 39(3), 527-532.

Vancouver

Kizhnyaev VN, Gorkovenko OP, Safronov AP, Adamova LV. Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water. Vysokomolekulyarnye soedineniya Seriya A & Seriya B. 1997 март;39(3):527-532.

Author

Kizhnyaev, V. N. ; Gorkovenko, O. P. ; Safronov, A. P. и др. / Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water. в: Vysokomolekulyarnye soedineniya Seriya A & Seriya B. 1997 ; Том 39, № 3. стр. 527-532.

BibTeX

@article{bc429c99574e47e09647deb458b34de3,
title = "Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water",
abstract = "Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water was studied at 298 K. The Gibbs free energies, enthalpies, and entropies of mixing are negative for the dissolution and swelling of poly(C-vinyltetrazoles) in water. For un-ionized polyacids the plots of the enthalpies of dilution (mixing) for un-ionized polyacids versus the composition of polymer-water system exhibit additional extrema at a water content 10-20%. This fact is explained by the ''ordering'' and the ''disorderings'' effects of water. The affinity of poly(C-vinyltetrazoles) to water is significantly enhanced on ionization of the polymers considered. The changes in the thermodynamic parameters of polymer dissolution depend on the conformational state of macromolecules, which is determined by their hydrophilic-hydrophobic balance.",
author = "Kizhnyaev, {V. N.} and Gorkovenko, {O. P.} and Safronov, {A. P.} and Adamova, {L. V.}",
year = "1997",
month = mar,
language = "Русский",
volume = "39",
pages = "527--532",
journal = "Vysokomolekulyarnye soedineniya Seriya A & Seriya B",
issn = "0507-5475",
publisher = "Редакция журнала {"}Высокомолекулярные соединения{"}",
number = "3",

}

RIS

TY - JOUR

T1 - Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water

AU - Kizhnyaev, V. N.

AU - Gorkovenko, O. P.

AU - Safronov, A. P.

AU - Adamova, L. V.

PY - 1997/3

Y1 - 1997/3

N2 - Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water was studied at 298 K. The Gibbs free energies, enthalpies, and entropies of mixing are negative for the dissolution and swelling of poly(C-vinyltetrazoles) in water. For un-ionized polyacids the plots of the enthalpies of dilution (mixing) for un-ionized polyacids versus the composition of polymer-water system exhibit additional extrema at a water content 10-20%. This fact is explained by the ''ordering'' and the ''disorderings'' effects of water. The affinity of poly(C-vinyltetrazoles) to water is significantly enhanced on ionization of the polymers considered. The changes in the thermodynamic parameters of polymer dissolution depend on the conformational state of macromolecules, which is determined by their hydrophilic-hydrophobic balance.

AB - Thermodynamics of the interaction between tetrazole-containing polyelectrolytes and water was studied at 298 K. The Gibbs free energies, enthalpies, and entropies of mixing are negative for the dissolution and swelling of poly(C-vinyltetrazoles) in water. For un-ionized polyacids the plots of the enthalpies of dilution (mixing) for un-ionized polyacids versus the composition of polymer-water system exhibit additional extrema at a water content 10-20%. This fact is explained by the ''ordering'' and the ''disorderings'' effects of water. The affinity of poly(C-vinyltetrazoles) to water is significantly enhanced on ionization of the polymers considered. The changes in the thermodynamic parameters of polymer dissolution depend on the conformational state of macromolecules, which is determined by their hydrophilic-hydrophobic balance.

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=A1997WX33500022

M3 - Статья

VL - 39

SP - 527

EP - 532

JO - Vysokomolekulyarnye soedineniya Seriya A & Seriya B

JF - Vysokomolekulyarnye soedineniya Seriya A & Seriya B

SN - 0507-5475

IS - 3

ER -

ID: 8965419