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Reaction of 1,2,4-Triazine-5-carbonitriles with 5-[(2-Hydroxyethyl)sulfanyl]- and 5-{[2-(2-Hydroxyethoxy)-ethyl]sulfanyl}-3-amino-1,2,4-triazoles1. / Krinochkin, A. P.; Ladin, E. D.; Shtaitz, Ya. K. и др.
в: Russian Journal of Organic Chemistry, Том 59, № 11, 01.11.2023, стр. 1998-2002.

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@article{67ed0e2eb10b48f58decc0b9ca1c7950,
title = "Reaction of 1,2,4-Triazine-5-carbonitriles with 5-[(2-Hydroxyethyl)sulfanyl]- and 5-{[2-(2-Hydroxyethoxy)-ethyl]sulfanyl}-3-amino-1,2,4-triazoles1",
abstract = "The solvent-free reaction of 1,2,4-triazine-5-carbonitriles with newly synthesized 5-[(2-hydroxyethyl)sulfanyl]- and 5-{[2-(2-hydroxyethoxy)ethyl]sulfanyl}-3-amino-1,2,4-triazoles under heating was studied. It was shown that in the case when the C5 atom of the 1,2,4-triazole ring bears hydroxy(ethoxy)ethylsulfanyl substituents, 5-amino-1,2,4-triazines are formed as the main reaction products, while the ipso-substitution products of the C5-cyano group of the substituted 1,2,4-triazole ring were isolated only as by-products. With a 1,2,4-triazole with a monoethylene glycol fragment at the C5 position, a complex mixture of products was formed.",
author = "Krinochkin, {A. P.} and Ladin, {E. D.} and Shtaitz, {Ya. K.} and Kudryashova, {E. A.} and Kopchuk, {D. S.} and Gorbunov, {E. B.} and Shafran, {Yu. M.} and Zyryanov, {G. V.} and Rusinov, {V. L.}",
note = "The work was financially supported by the Russian Science Foundation (project no. 20-13-00142-P, https://rscf.ru/project/20-13-00142/, synthesis of the final products) and Grant Council under the President of the Russian Federation (grant no. MD-167.2021.1.3, synthesis of the starting aminotriazoles).",
year = "2023",
month = nov,
day = "1",
doi = "10.1134/S1070428023110210",
language = "English",
volume = "59",
pages = "1998--2002",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "11",

}

RIS

TY - JOUR

T1 - Reaction of 1,2,4-Triazine-5-carbonitriles with 5-[(2-Hydroxyethyl)sulfanyl]- and 5-{[2-(2-Hydroxyethoxy)-ethyl]sulfanyl}-3-amino-1,2,4-triazoles1

AU - Krinochkin, A. P.

AU - Ladin, E. D.

AU - Shtaitz, Ya. K.

AU - Kudryashova, E. A.

AU - Kopchuk, D. S.

AU - Gorbunov, E. B.

AU - Shafran, Yu. M.

AU - Zyryanov, G. V.

AU - Rusinov, V. L.

N1 - The work was financially supported by the Russian Science Foundation (project no. 20-13-00142-P, https://rscf.ru/project/20-13-00142/, synthesis of the final products) and Grant Council under the President of the Russian Federation (grant no. MD-167.2021.1.3, synthesis of the starting aminotriazoles).

PY - 2023/11/1

Y1 - 2023/11/1

N2 - The solvent-free reaction of 1,2,4-triazine-5-carbonitriles with newly synthesized 5-[(2-hydroxyethyl)sulfanyl]- and 5-{[2-(2-hydroxyethoxy)ethyl]sulfanyl}-3-amino-1,2,4-triazoles under heating was studied. It was shown that in the case when the C5 atom of the 1,2,4-triazole ring bears hydroxy(ethoxy)ethylsulfanyl substituents, 5-amino-1,2,4-triazines are formed as the main reaction products, while the ipso-substitution products of the C5-cyano group of the substituted 1,2,4-triazole ring were isolated only as by-products. With a 1,2,4-triazole with a monoethylene glycol fragment at the C5 position, a complex mixture of products was formed.

AB - The solvent-free reaction of 1,2,4-triazine-5-carbonitriles with newly synthesized 5-[(2-hydroxyethyl)sulfanyl]- and 5-{[2-(2-hydroxyethoxy)ethyl]sulfanyl}-3-amino-1,2,4-triazoles under heating was studied. It was shown that in the case when the C5 atom of the 1,2,4-triazole ring bears hydroxy(ethoxy)ethylsulfanyl substituents, 5-amino-1,2,4-triazines are formed as the main reaction products, while the ipso-substitution products of the C5-cyano group of the substituted 1,2,4-triazole ring were isolated only as by-products. With a 1,2,4-triazole with a monoethylene glycol fragment at the C5 position, a complex mixture of products was formed.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85184440194

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001157742100020

UR - https://elibrary.ru/item.asp?id=64732598

U2 - 10.1134/S1070428023110210

DO - 10.1134/S1070428023110210

M3 - Article

VL - 59

SP - 1998

EP - 2002

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 11

ER -

ID: 52961029