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DOI

The formation of two independent paramagnetic centres Ru(JT) and Ru(A) was detected by the EPR method LiH and LiD single crystals doped with ruthenium, after illumination with visible light at T=77 K. Both centres were assigned to Ru+ with low-spin 4d7 configuration. Ru(JT) centres exhibit a quasidynamical Jahn-Teller effect. The values of tunnelling splitting 3 Gamma and random-strain splitting delta were estimated to be 24 cm -1 and 6.0 cm-1, respectively. The Ru(A) centre was found to have tetragonal symmetry with the unpaired electron in a 4d(3z 2-r2) orbital.
Язык оригиналаАнглийский
Страницы (с-по)4047-4054
Число страниц8
ЖурналJournal of Physics Condensed Matter
Том4
Номер выпуска15
DOI
СостояниеОпубликовано - 13 апр. 1992

    Предметные области ASJC Scopus

  • Condensed Matter Physics
  • Материаловедение в целом

ID: 55804239