New Binuclear Copper(II) Complex Based on 1,2-Bis(2-(4,4,4-trifluoro-1,3-dioxobutyl)phenoxyethane: Synthesis and Structure

Standard

New Binuclear Copper(II) Complex Based on 1,2-Bis(2-(4,4,4-trifluoro-1,3-dioxobutyl)phenoxyethane: Synthesis and Structure. / Patrina, A. N.; Veretennikova, E. A.; Khamidullina, L. A. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 49, № 1, 2023, стр. 41-46.

Результаты исследований: Вклад в журнал › Статья › Рецензирование

Author

Patrina, A. N. ; Veretennikova, E. A. ; Khamidullina, L. A. и др. / New Binuclear Copper(II) Complex Based on 1,2-Bis(2-(4,4,4-trifluoro-1,3-dioxobutyl)phenoxyethane: Synthesis and Structure. в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023 ; Том 49, № 1. стр. 41-46.

BibTeX

@article{d1ba2eeef2fc407ba3d61ed217af38e5,

title = "New Binuclear Copper(II) Complex Based on 1,2-Bis(2-(4,4,4-trifluoro-1,3-dioxobutyl)phenoxyethane: Synthesis and Structure",

abstract = "New binuclear complex 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethanedi(dimethylformamide)dicopper(II) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2179252). A crystal of the complex is formed by centrosymmetric Cu2L2(DMF)2 molecules in which the coordination environment of each metallocenter is a distorted square pyramid, and the whole molecule is a metallomacrocycle containing the calixarene-like cavity. Its size is determined the distance between the Cu…Cu metallocenters (7.699 {\AA}) and the distance between the planes of the opposite phenyl radicals in the cis position (8.200–8.323 {\AA}). The cavity is a parallelogram. The carcass-type binuclear structure is formed due to an increase in the denticity of the ligand via the formation of the bis(triketone)-like structure that weakens the donor character of both functional groups of the β-diketone fragment.",

author = "Patrina, {A. N.} and Veretennikova, {E. A.} and Khamidullina, {L. A.} and Puzyrev, {I. S.} and Slepukhin, {P. A.} and Pestov, {A. V.}",

note = "This work was carried out within the framework of the state assignment of the Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences (topic АААА-А19-119011790132-7) and with the support of the Russian Foundation for Basic Research (grant no. 20-43-660042) using the equipment of the Center for Collective Use “Spectroscopy and Analysis of Organic Compounds.”",

year = "2023",

doi = "10.1134/S1070328422700300",

language = "English",

volume = "49",

pages = "41--46",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "1",

}

RIS

TY - JOUR

T1 - New Binuclear Copper(II) Complex Based on 1,2-Bis(2-(4,4,4-trifluoro-1,3-dioxobutyl)phenoxyethane: Synthesis and Structure

AU - Patrina, A. N.

AU - Veretennikova, E. A.

AU - Khamidullina, L. A.

AU - Puzyrev, I. S.

AU - Slepukhin, P. A.

AU - Pestov, A. V.

N1 - This work was carried out within the framework of the state assignment of the Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences (topic АААА-А19-119011790132-7) and with the support of the Russian Foundation for Basic Research (grant no. 20-43-660042) using the equipment of the Center for Collective Use “Spectroscopy and Analysis of Organic Compounds.”

PY - 2023

Y1 - 2023

N2 - New binuclear complex 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethanedi(dimethylformamide)dicopper(II) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2179252). A crystal of the complex is formed by centrosymmetric Cu2L2(DMF)2 molecules in which the coordination environment of each metallocenter is a distorted square pyramid, and the whole molecule is a metallomacrocycle containing the calixarene-like cavity. Its size is determined the distance between the Cu…Cu metallocenters (7.699 Å) and the distance between the planes of the opposite phenyl radicals in the cis position (8.200–8.323 Å). The cavity is a parallelogram. The carcass-type binuclear structure is formed due to an increase in the denticity of the ligand via the formation of the bis(triketone)-like structure that weakens the donor character of both functional groups of the β-diketone fragment.

AB - New binuclear complex 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethanedi(dimethylformamide)dicopper(II) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2179252). A crystal of the complex is formed by centrosymmetric Cu2L2(DMF)2 molecules in which the coordination environment of each metallocenter is a distorted square pyramid, and the whole molecule is a metallomacrocycle containing the calixarene-like cavity. Its size is determined the distance between the Cu…Cu metallocenters (7.699 Å) and the distance between the planes of the opposite phenyl radicals in the cis position (8.200–8.323 Å). The cavity is a parallelogram. The carcass-type binuclear structure is formed due to an increase in the denticity of the ligand via the formation of the bis(triketone)-like structure that weakens the donor character of both functional groups of the β-diketone fragment.

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UR - https://elibrary.ru/item.asp?id=61278723

U2 - 10.1134/S1070328422700300

DO - 10.1134/S1070328422700300

M3 - Article

VL - 49

SP - 41

EP - 46

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 1

ER -

ID: 38532891