Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Ionic solvation and the electrical conductivity of lithium salt solutions in an acrylonitrile-butadiene copolymer
AU - Bushkova, O. V.
AU - Lirova, B. I.
AU - Zhukovskii, V. M.
PY - 1999
Y1 - 1999
N2 - IR spectroscopy is used to study ion-molecule interactions in macromolecular ionic solutions of lithium salts (LiClO4, LiCF3SO3, LiAsF6) in an acrylonitrile-butadiene (SKN-40) copolymer. There is a correlation between ion-molecule interactions and the electrical conductivity, measured by the method of electrochemical impedance in the temperature range 20-100°C. The processes of ionic solvation in SKN-40 and acetonitrile, a nonaqueous liquid solvent of similar chemical nature, are similar. It was also shown that small amounts of methyl ethyl ketone influence ionic transport in SKN-40.
AB - IR spectroscopy is used to study ion-molecule interactions in macromolecular ionic solutions of lithium salts (LiClO4, LiCF3SO3, LiAsF6) in an acrylonitrile-butadiene (SKN-40) copolymer. There is a correlation between ion-molecule interactions and the electrical conductivity, measured by the method of electrochemical impedance in the temperature range 20-100°C. The processes of ionic solvation in SKN-40 and acetonitrile, a nonaqueous liquid solvent of similar chemical nature, are similar. It was also shown that small amounts of methyl ethyl ketone influence ionic transport in SKN-40.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0033239122
M3 - Article
VL - 73
SP - 735
EP - 738
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 5
ER -
ID: 56190403