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Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate. / Alizadeh, Vali; Mahmoudi, Ghodrat; Priola, Emanuele и др.
в: Inorganic Chemistry Communications, Том 149, 110393, 01.03.2023.

Результаты исследований: Вклад в журнал › Статья › Рецензирование

Harvard

Alizadeh, V, Mahmoudi, G, Priola, E, Seth, SK, White, JM, Frontera, A & Safin, DA 2023, 'Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate', Inorganic Chemistry Communications, Том. 149, 110393. https://doi.org/10.1016/j.inoche.2023.110393

APA

Alizadeh, V., Mahmoudi, G., Priola, E., Seth, S. K., White, J. M., Frontera, A., & Safin, D. A. (2023). Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate. Inorganic Chemistry Communications, 149, [110393]. https://doi.org/10.1016/j.inoche.2023.110393

Vancouver

Alizadeh V, Mahmoudi G, Priola E, Seth SK, White JM, Frontera A и др. Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate. Inorganic Chemistry Communications. 2023 март 1;149:110393. doi: 10.1016/j.inoche.2023.110393

Author

Alizadeh, Vali ; Mahmoudi, Ghodrat ; Priola, Emanuele и др. / Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate. в: Inorganic Chemistry Communications. 2023 ; Том 149.

BibTeX

@article{cf374d10b1544d1992da976a7064a54d,
title = "Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A M{\"o}bius-like discrete metal chelate",
abstract = "In this work we have synthesized and characterized a new coordination compound [HgL(ClO4)2EtOH] (1), fabricated from a mixture of Hg(NO3)2 and NaClO4 with 1,2-diphenyl-1,2-bis((phenyl-(pyridin-2-yl)methylene)hydrazono)ethane (L). Single-crystal X-ray crystallography revealed the formation of a mononuclear heteroleptic discrete structure with one molecule [HgL(ClO4)2EtOH] in the asymmetric unit. The ligand L adopts a helical twist conformation. The Hg(II) cation is coordinated by four nitrogen atoms from L and by three oxygen atoms from two monocoordinated ClO4– anions and one ethanol molecule. The crystal structure of 1 is stabilized by the intermolecular O–H⋯O hydrogen bonds, and Cl–O⋯πPh and C–H⋯πPh interactions, yielding a supramolecular 3D framework. Moreover, the long Hg–N/O bonds have been analyzed in terms of coordination, semicoordination or spodium bonds using QTAIM and NCIplot index computational tools.",
author = "Vali Alizadeh and Ghodrat Mahmoudi and Emanuele Priola and Seth, {Saikat Kumar} and White, {Jonathan M.} and Antonio Frontera and Safin, {Damir A.}",
note = "This research was funded by MICIU/AEI, grant number CTQ2017-85821-R, FEDER funds.",
year = "2023",
month = mar,
day = "1",
doi = "10.1016/j.inoche.2023.110393",
language = "English",
volume = "149",
journal = "Inorganic Chemistry Communications",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate

AU - Alizadeh, Vali

AU - Mahmoudi, Ghodrat

AU - Priola, Emanuele

AU - Seth, Saikat Kumar

AU - White, Jonathan M.

AU - Frontera, Antonio

AU - Safin, Damir A.

N1 - This research was funded by MICIU/AEI, grant number CTQ2017-85821-R, FEDER funds.

PY - 2023/3/1

Y1 - 2023/3/1

N2 - In this work we have synthesized and characterized a new coordination compound [HgL(ClO4)2EtOH] (1), fabricated from a mixture of Hg(NO3)2 and NaClO4 with 1,2-diphenyl-1,2-bis((phenyl-(pyridin-2-yl)methylene)hydrazono)ethane (L). Single-crystal X-ray crystallography revealed the formation of a mononuclear heteroleptic discrete structure with one molecule [HgL(ClO4)2EtOH] in the asymmetric unit. The ligand L adopts a helical twist conformation. The Hg(II) cation is coordinated by four nitrogen atoms from L and by three oxygen atoms from two monocoordinated ClO4– anions and one ethanol molecule. The crystal structure of 1 is stabilized by the intermolecular O–H⋯O hydrogen bonds, and Cl–O⋯πPh and C–H⋯πPh interactions, yielding a supramolecular 3D framework. Moreover, the long Hg–N/O bonds have been analyzed in terms of coordination, semicoordination or spodium bonds using QTAIM and NCIplot index computational tools.

AB - In this work we have synthesized and characterized a new coordination compound [HgL(ClO4)2EtOH] (1), fabricated from a mixture of Hg(NO3)2 and NaClO4 with 1,2-diphenyl-1,2-bis((phenyl-(pyridin-2-yl)methylene)hydrazono)ethane (L). Single-crystal X-ray crystallography revealed the formation of a mononuclear heteroleptic discrete structure with one molecule [HgL(ClO4)2EtOH] in the asymmetric unit. The ligand L adopts a helical twist conformation. The Hg(II) cation is coordinated by four nitrogen atoms from L and by three oxygen atoms from two monocoordinated ClO4– anions and one ethanol molecule. The crystal structure of 1 is stabilized by the intermolecular O–H⋯O hydrogen bonds, and Cl–O⋯πPh and C–H⋯πPh interactions, yielding a supramolecular 3D framework. Moreover, the long Hg–N/O bonds have been analyzed in terms of coordination, semicoordination or spodium bonds using QTAIM and NCIplot index computational tools.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85146463745

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000923706800001

U2 - 10.1016/j.inoche.2023.110393

DO - 10.1016/j.inoche.2023.110393

M3 - Article

VL - 149

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

SN - 1387-7003

M1 - 110393

ER -

ID: 33986979