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Formation of yttrium oxalate phase filled by carbon clusters on the surface of yttrium oxide films. / Boukhvalov, D.; Zatsepin, D.; Biryukov, D. и др.
в: Materials Chemistry and Physics, Том 315, 128936, 01.03.2024.

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@article{0285aa7247194db9bb7fa258cb35d5e4,
title = "Formation of yttrium oxalate phase filled by carbon clusters on the surface of yttrium oxide films",
abstract = "In the current paper, we report the results of surface modification of cubic Y2O3 films employing carbon-ion implantation. The characterization results demonstrate the formation of a stable yttrium oxalate-based structure with cavities filled with carbon clusters. Theoretical simulations demonstrate that the incorporation of eighteen-atom carbon clusters into the cavities of Y2(C2O4)3 does not lead to valuable changes in the crystal structure of yttrium oxalate. X-ray diffraction and optical measurements demonstrate that the subsurface bulk area of cubic yttrium oxide remains unperturbed. The oxalate “skin” thickness with embedded carbon clusters is estimated to be approximately 10 nm. The prospective employing the method to manage optical properties and increase the biocompatibility of yttria and lanthanide oxides are discussed.",
author = "D. Boukhvalov and D. Zatsepin and D. Biryukov and Yu. Shchapova and N. Gavrilov and A. Zatsepin",
note = "The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Anatoly Zatsepin reports financial support was provided by Ministry of Science and Higher Education of Russian Federation.The study was supported by the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program, project 4.38).",
year = "2024",
month = mar,
day = "1",
doi = "10.1016/j.matchemphys.2024.128936",
language = "English",
volume = "315",
journal = "Materials Chemistry and Physics",
issn = "0254-0584",
publisher = "Elsevier BV",

}

RIS

TY - JOUR

T1 - Formation of yttrium oxalate phase filled by carbon clusters on the surface of yttrium oxide films

AU - Boukhvalov, D.

AU - Zatsepin, D.

AU - Biryukov, D.

AU - Shchapova, Yu.

AU - Gavrilov, N.

AU - Zatsepin, A.

N1 - The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Anatoly Zatsepin reports financial support was provided by Ministry of Science and Higher Education of Russian Federation.The study was supported by the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program, project 4.38).

PY - 2024/3/1

Y1 - 2024/3/1

N2 - In the current paper, we report the results of surface modification of cubic Y2O3 films employing carbon-ion implantation. The characterization results demonstrate the formation of a stable yttrium oxalate-based structure with cavities filled with carbon clusters. Theoretical simulations demonstrate that the incorporation of eighteen-atom carbon clusters into the cavities of Y2(C2O4)3 does not lead to valuable changes in the crystal structure of yttrium oxalate. X-ray diffraction and optical measurements demonstrate that the subsurface bulk area of cubic yttrium oxide remains unperturbed. The oxalate “skin” thickness with embedded carbon clusters is estimated to be approximately 10 nm. The prospective employing the method to manage optical properties and increase the biocompatibility of yttria and lanthanide oxides are discussed.

AB - In the current paper, we report the results of surface modification of cubic Y2O3 films employing carbon-ion implantation. The characterization results demonstrate the formation of a stable yttrium oxalate-based structure with cavities filled with carbon clusters. Theoretical simulations demonstrate that the incorporation of eighteen-atom carbon clusters into the cavities of Y2(C2O4)3 does not lead to valuable changes in the crystal structure of yttrium oxalate. X-ray diffraction and optical measurements demonstrate that the subsurface bulk area of cubic yttrium oxide remains unperturbed. The oxalate “skin” thickness with embedded carbon clusters is estimated to be approximately 10 nm. The prospective employing the method to manage optical properties and increase the biocompatibility of yttria and lanthanide oxides are discussed.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85182735928

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001170500800001

U2 - 10.1016/j.matchemphys.2024.128936

DO - 10.1016/j.matchemphys.2024.128936

M3 - Article

VL - 315

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

M1 - 128936

ER -

ID: 51601167