TY - JOUR

T1 - Fluorine-insertion in solid oxide materials for improving their ionic transport and stability. A brief review

AU - Tarasova, Nataliia

AU - Hanif, Muhammad

AU - Janjua, Naveed

AU - Anwar, Shahid

AU - Motola, Martin

AU - Medvedev, Dmitry

N1 - This work is supported by the Ministry of Education and Science of the Russian Federation (contract no. FEUZ-2023-0018 (0.75-03-2023-006/1)). Dr. M.H. Hanif and Dr. M. Motola thank to the Scientific Grant Agency of the Slovak Ministry of Education , Sciences, Research and Sport ( VEGA ) # 1/0319/23, Grant of the Comenius University Bratislava for Young Scientists (UK/24/2023).

PY - 2024

Y1 - 2024

N2 - Materials engineering is an important trajectory for the design of new complex oxide compounds for their high-temperature application in solid oxide electrochemical cells. Usually, tailoring the functional properties of such compounds is realized through a cationic-type doping strategy, when a partial substitution of basic cations with impurity ions is performed. Typically, such a doping improves some properties, but deteriorates others due to significant changes in the cationic framework of a crystal. Anionic-type doping is an alternative way to leave the cationic sites unchanged, which may be suitable for achieving a compromise between a variety of properties. In this brief review, we summarize the existing data devoted to the F-doping (or F-insertion) of solid oxide electrolyte and electrode materials. In most cases, the F-doping improves the chemical stability of compounds and their ionic transport properties. Possible reasons responsible for this improvement are briefly discussed. In addition to highlighting these advantages, possible drawbacks are also listed to stimulate further research activities on this problem.

AB - Materials engineering is an important trajectory for the design of new complex oxide compounds for their high-temperature application in solid oxide electrochemical cells. Usually, tailoring the functional properties of such compounds is realized through a cationic-type doping strategy, when a partial substitution of basic cations with impurity ions is performed. Typically, such a doping improves some properties, but deteriorates others due to significant changes in the cationic framework of a crystal. Anionic-type doping is an alternative way to leave the cationic sites unchanged, which may be suitable for achieving a compromise between a variety of properties. In this brief review, we summarize the existing data devoted to the F-doping (or F-insertion) of solid oxide electrolyte and electrode materials. In most cases, the F-doping improves the chemical stability of compounds and their ionic transport properties. Possible reasons responsible for this improvement are briefly discussed. In addition to highlighting these advantages, possible drawbacks are also listed to stimulate further research activities on this problem.

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U2 - 10.1016/j.ijhydene.2023.08.074

DO - 10.1016/j.ijhydene.2023.08.074

M3 - Review article

VL - 50

SP - 104

EP - 123

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

ER -