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EPR detection of Cr4+ centers in yttrium orthosilicate Y2SiO5. / Potapov, A.; Vazhenin, V.; Artyomov, M. и др.
в: Optical Materials, Том 143, 114149, 09.2023.

Результаты исследований: Вклад в журналСтатьяРецензирование

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Potapov A, Vazhenin V, Artyomov M, Shakurov G, Zaripov RB, Subbotin K и др. EPR detection of Cr4+ centers in yttrium orthosilicate Y2SiO5. Optical Materials. 2023 сент.;143:114149. doi: 10.1016/j.optmat.2023.114149

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BibTeX

@article{d4a9574b489a49f78612bf852ecda7e4,
title = "EPR detection of Cr4+ centers in yttrium orthosilicate Y2SiO5",
abstract = "The EPR spectra of Czochralski grown Y2SiO5:Cr and Y2SiO5:53Cr crystals have been studied. In addition to the previously known spectra of Cr3+, the spectrum of the Cr4+ ion was detected and studied for the first time. The fine structure parameters of tetravalent chromium in Y2SiO5 host were obtained based on the analysis of the angular and frequency-field dependences of the EPR spectra. The conclusion about tetrahedral coordination of Cr4+ ion in this host was made. The concentrations ratio of c(Cr3+)/c(Cr4+) ions in the crystal has been evaluated.",
author = "A. Potapov and V. Vazhenin and M. Artyomov and G. Shakurov and Zaripov, {Ruslan B.} and K. Subbotin and Shestakov, {Aleksei V.}",
note = "The research work of the authors from Ural Federal University was supported by the Ministry of Science and Higher Education of the Russian Federation (grant FEUZ-2023-0017 ) using the equipment of the Ural Center of Shared Facilities “Modern Nanotechnologies”. The authors from Zavoisky Physical-Technical Institute acknowledge the financial support from the government assignment for FRC Kazan Scientific Center of RAS.",
year = "2023",
month = sep,
doi = "10.1016/j.optmat.2023.114149",
language = "English",
volume = "143",
journal = "Optical Materials",
issn = "0925-3467",
publisher = "Elsevier BV",

}

RIS

TY - JOUR

T1 - EPR detection of Cr4+ centers in yttrium orthosilicate Y2SiO5

AU - Potapov, A.

AU - Vazhenin, V.

AU - Artyomov, M.

AU - Shakurov, G.

AU - Zaripov, Ruslan B.

AU - Subbotin, K.

AU - Shestakov, Aleksei V.

N1 - The research work of the authors from Ural Federal University was supported by the Ministry of Science and Higher Education of the Russian Federation (grant FEUZ-2023-0017 ) using the equipment of the Ural Center of Shared Facilities “Modern Nanotechnologies”. The authors from Zavoisky Physical-Technical Institute acknowledge the financial support from the government assignment for FRC Kazan Scientific Center of RAS.

PY - 2023/9

Y1 - 2023/9

N2 - The EPR spectra of Czochralski grown Y2SiO5:Cr and Y2SiO5:53Cr crystals have been studied. In addition to the previously known spectra of Cr3+, the spectrum of the Cr4+ ion was detected and studied for the first time. The fine structure parameters of tetravalent chromium in Y2SiO5 host were obtained based on the analysis of the angular and frequency-field dependences of the EPR spectra. The conclusion about tetrahedral coordination of Cr4+ ion in this host was made. The concentrations ratio of c(Cr3+)/c(Cr4+) ions in the crystal has been evaluated.

AB - The EPR spectra of Czochralski grown Y2SiO5:Cr and Y2SiO5:53Cr crystals have been studied. In addition to the previously known spectra of Cr3+, the spectrum of the Cr4+ ion was detected and studied for the first time. The fine structure parameters of tetravalent chromium in Y2SiO5 host were obtained based on the analysis of the angular and frequency-field dependences of the EPR spectra. The conclusion about tetrahedral coordination of Cr4+ ion in this host was made. The concentrations ratio of c(Cr3+)/c(Cr4+) ions in the crystal has been evaluated.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85165530492

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001047479600001

U2 - 10.1016/j.optmat.2023.114149

DO - 10.1016/j.optmat.2023.114149

M3 - Article

VL - 143

JO - Optical Materials

JF - Optical Materials

SN - 0925-3467

M1 - 114149

ER -

ID: 43273289