Результаты исследований: Вклад в журнал › Статья › Рецензирование
Результаты исследований: Вклад в журнал › Статья › Рецензирование
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TY - JOUR
T1 - Development and study of lightweight recycled composite materials based on linear low-density polyethylene and W for radiation application
AU - Rotkovich, A. A.
AU - Tishkevich, D. I.
AU - Razanau, I. U.
AU - Vershinina, T. N.
AU - Bondaruk, A. A.
AU - German, S. A.
AU - Zubar, T. I.
AU - Sayyed, M. I.
AU - Dong, M.
AU - Yao, Yuan
AU - Mahmoud, K. A.
AU - Silibin, M. V.
AU - Trukhanov, A. V.
N1 - This research was funded by the Belarusian Republican Foundation for Fundamental Research (project No. T23ME-005). M. Silibin acknowledge the Academic leadership program Priority 2030 proposed by Federal State Autonomous Educational Institution of Higher Education I.M. Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation (Sechenov University). Y. Yao acknowledges the National Natural Science Foundation of China (Grant No. U2067216).
PY - 2024/5/1
Y1 - 2024/5/1
N2 - Composite materials based on a polymer matrix of linear low-density polyethylene (LLDPE) and W were produced by thermal pressing. The content of W in the samples varied from 0 to 70 %. The recycling properties of LLDPE are demonstrated in this study, which significantly helped to reduce the defects. The microstructure of the composites consists of well-defined W grains covered by elastic LLDPE fibers. A homogeneous distribution of tungsten in the polymer matrix was observed for sample W70. The EDX analysis showed the presence of tungsten and carbon (from the polymer component). The XRD analysis confirms the increase in W content in the samples. The FTIR spectra of the composites showed an increase in the content of terminal methyl groups, a decrease in the molecular weight, and a decrease in the degree of crystallinity of the polyethylene matrix with an increase in the W content in the composite. The sample with 70 % W content has the highest effective density (2.61 g/cm3). The sample relative density ranges from 93.3 to 97.7 %. The porosity of LLDPE-W composites does not exceed 7 %. Gamma radiation shielding efficiency parameters such as LAC, HVL, and MFP were calculated using Phy-X/PSD. The radiation source was Co60, with an emission range of 0.8–2.5 MeV. As the gamma energy increases, it is observed that the values of all the parameters deteriorate. However, the sample with a maximum W content of 70 % has the best values of LAC, HVL, and MFP among the other samples.
AB - Composite materials based on a polymer matrix of linear low-density polyethylene (LLDPE) and W were produced by thermal pressing. The content of W in the samples varied from 0 to 70 %. The recycling properties of LLDPE are demonstrated in this study, which significantly helped to reduce the defects. The microstructure of the composites consists of well-defined W grains covered by elastic LLDPE fibers. A homogeneous distribution of tungsten in the polymer matrix was observed for sample W70. The EDX analysis showed the presence of tungsten and carbon (from the polymer component). The XRD analysis confirms the increase in W content in the samples. The FTIR spectra of the composites showed an increase in the content of terminal methyl groups, a decrease in the molecular weight, and a decrease in the degree of crystallinity of the polyethylene matrix with an increase in the W content in the composite. The sample with 70 % W content has the highest effective density (2.61 g/cm3). The sample relative density ranges from 93.3 to 97.7 %. The porosity of LLDPE-W composites does not exceed 7 %. Gamma radiation shielding efficiency parameters such as LAC, HVL, and MFP were calculated using Phy-X/PSD. The radiation source was Co60, with an emission range of 0.8–2.5 MeV. As the gamma energy increases, it is observed that the values of all the parameters deteriorate. However, the sample with a maximum W content of 70 % has the best values of LAC, HVL, and MFP among the other samples.
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U2 - 10.1016/j.jmrt.2024.03.187
DO - 10.1016/j.jmrt.2024.03.187
M3 - Article
VL - 30
SP - 1310
EP - 1318
JO - Journal of Materials Research and Technology
JF - Journal of Materials Research and Technology
SN - 2238-7854
ER -
ID: 55354169