Standard

Universal equation for estimation of values of conventional standard electrode potentials. / Lebedev, V. A.
In: Rasplavy, No. 1, 1992, p. 87-90.

Research output: Contribution to journal › Article › peer-review

Harvard

Lebedev, VA 1992, 'Universal equation for estimation of values of conventional standard electrode potentials', Rasplavy, no. 1, pp. 87-90.

APA

Lebedev, V. A. (1992). Universal equation for estimation of values of conventional standard electrode potentials. Rasplavy, (1), 87-90.

Vancouver

Lebedev VA. Universal equation for estimation of values of conventional standard electrode potentials. Rasplavy. 1992;(1):87-90.

Author

Lebedev, V. A. / Universal equation for estimation of values of conventional standard electrode potentials. In: Rasplavy. 1992 ; No. 1. pp. 87-90.

BibTeX

@article{df5a4b65666745a29dd068cac2154155,
title = "Universal equation for estimation of values of conventional standard electrode potentials",
abstract = "A general-purpose equation has been proposed for the dependence of conditional standard potential, E*, on the effective radius of the solvent cation and on the ionic momentum of the potential-determining element. It is found that the application of E* markedly increases the accuracy and confidence of equilibrium potential estimates, since the E* unlike standard potentials, E0, may be directly and precisely measured (the reproducibility of the E* independent measurements is within ± 0.01 v). The proposed equation is tested by the measured data on E* for Mg2+/Mg in different salt solvents. This equation makes it possible to estimate the temperature dependence of E* in any melt from that calculated for one solvent.",
author = "Lebedev, {V. A.}",
year = "1992",
language = "Русский",
pages = "87--90",
journal = "Rasplavy",
issn = "0235-0106",
publisher = "Издательство {"}Наука{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Universal equation for estimation of values of conventional standard electrode potentials

AU - Lebedev, V. A.

PY - 1992

Y1 - 1992

N2 - A general-purpose equation has been proposed for the dependence of conditional standard potential, E*, on the effective radius of the solvent cation and on the ionic momentum of the potential-determining element. It is found that the application of E* markedly increases the accuracy and confidence of equilibrium potential estimates, since the E* unlike standard potentials, E0, may be directly and precisely measured (the reproducibility of the E* independent measurements is within ± 0.01 v). The proposed equation is tested by the measured data on E* for Mg2+/Mg in different salt solvents. This equation makes it possible to estimate the temperature dependence of E* in any melt from that calculated for one solvent.

AB - A general-purpose equation has been proposed for the dependence of conditional standard potential, E*, on the effective radius of the solvent cation and on the ionic momentum of the potential-determining element. It is found that the application of E* markedly increases the accuracy and confidence of equilibrium potential estimates, since the E* unlike standard potentials, E0, may be directly and precisely measured (the reproducibility of the E* independent measurements is within ± 0.01 v). The proposed equation is tested by the measured data on E* for Mg2+/Mg in different salt solvents. This equation makes it possible to estimate the temperature dependence of E* in any melt from that calculated for one solvent.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0026759973

M3 - Статья

SP - 87

EP - 90

JO - Rasplavy

JF - Rasplavy

SN - 0235-0106

IS - 1

ER -

ID: 54954749