Thermodynamics of mixing of crystalline poly(ethylene oxide) with amorphous poly(acrylates) and poly(methacrylates)

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Thermodynamics of mixing of crystalline poly(ethylene oxide) with amorphous poly(acrylates) and poly(methacrylates). / Suvorova, A. I.; Tyukova, I. S.; Khasanova, A. K.
In: Polymer Science - Series A, Vol. 43, No. 12, 2001, p. 1261-1265.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3350db8692bd4257985c107e1fddc979,

title = "Thermodynamics of mixing of crystalline poly(ethylene oxide) with amorphous poly(acrylates) and poly(methacrylates)",

abstract = "The interadtion with chloroform of crystalline poly(ethylene oxide) (PEO) and its blends with amorphous poly(methacrylate) (PMA), poly(methyl methacrylate) (PMMA), poly(butyl acrylate) (PBA), and poly(butyl methacrylate) (PBMA) was investigated using the static discrete sorption method. Calculations of the Gibbs mixing energy were carried out with allowance made for the degree of crystallinity of blends determined from X-ray diffraction data. The Gibbs energy of mixing with chloroform changes in the following order: PEO > PEO-PMA > PEO-PMMA > PEO-PBA = PEO-PBMA. The energies of mixing of crystalline PEO with amorphous polymers were calculated from the obtained Gibbs energies of mixing with chloroform. These energies fall in the range from -2.3 to -4.4 kJ/kg depending on the structure of the poly(acrylates).",

author = "Suvorova, {A. I.} and Tyukova, {I. S.} and Khasanova, {A. K.}",

year = "2001",

language = "English",

volume = "43",

pages = "1261--1265",

journal = "Polymer Science - Series A",

issn = "0965-545X",

publisher = "Pleiades Publishing",

number = "12",

}

RIS

TY - JOUR

T1 - Thermodynamics of mixing of crystalline poly(ethylene oxide) with amorphous poly(acrylates) and poly(methacrylates)

AU - Suvorova, A. I.

AU - Tyukova, I. S.

AU - Khasanova, A. K.

PY - 2001

Y1 - 2001

N2 - The interadtion with chloroform of crystalline poly(ethylene oxide) (PEO) and its blends with amorphous poly(methacrylate) (PMA), poly(methyl methacrylate) (PMMA), poly(butyl acrylate) (PBA), and poly(butyl methacrylate) (PBMA) was investigated using the static discrete sorption method. Calculations of the Gibbs mixing energy were carried out with allowance made for the degree of crystallinity of blends determined from X-ray diffraction data. The Gibbs energy of mixing with chloroform changes in the following order: PEO > PEO-PMA > PEO-PMMA > PEO-PBA = PEO-PBMA. The energies of mixing of crystalline PEO with amorphous polymers were calculated from the obtained Gibbs energies of mixing with chloroform. These energies fall in the range from -2.3 to -4.4 kJ/kg depending on the structure of the poly(acrylates).

AB - The interadtion with chloroform of crystalline poly(ethylene oxide) (PEO) and its blends with amorphous poly(methacrylate) (PMA), poly(methyl methacrylate) (PMMA), poly(butyl acrylate) (PBA), and poly(butyl methacrylate) (PBMA) was investigated using the static discrete sorption method. Calculations of the Gibbs mixing energy were carried out with allowance made for the degree of crystallinity of blends determined from X-ray diffraction data. The Gibbs energy of mixing with chloroform changes in the following order: PEO > PEO-PMA > PEO-PMMA > PEO-PBA = PEO-PBMA. The energies of mixing of crystalline PEO with amorphous polymers were calculated from the obtained Gibbs energies of mixing with chloroform. These energies fall in the range from -2.3 to -4.4 kJ/kg depending on the structure of the poly(acrylates).

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000173102200013

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0035528406

M3 - Article

VL - 43

SP - 1261

EP - 1265

JO - Polymer Science - Series A

JF - Polymer Science - Series A

SN - 0965-545X

IS - 12

ER -

ID: 44008641