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The effect of intermolecular interacations on magnetic shielding of nuclei of chemically bound atoms. / Terent'ev, S. N.; Zykov, P. G.
In: Chemical Physics Reports, Vol. 15, No. 8, 1996, p. 1231-1236.

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Terent'ev, SN & Zykov, PG 1996, 'The effect of intermolecular interacations on magnetic shielding of nuclei of chemically bound atoms', Chemical Physics Reports, vol. 15, no. 8, pp. 1231-1236.

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Author

Terent'ev, S. N. ; Zykov, P. G. / The effect of intermolecular interacations on magnetic shielding of nuclei of chemically bound atoms. In: Chemical Physics Reports. 1996 ; Vol. 15, No. 8. pp. 1231-1236.

BibTeX

@article{5686055d22e64eb98ecef1ab459389e8,
title = "The effect of intermolecular interacations on magnetic shielding of nuclei of chemically bound atoms",
abstract = "Temperature dependences of the second virial coefficients of 19F magnetic shielding due to pair CF4-X, SF6-X, X-Xe, Kr, and CH4 interactions in gas phase are determined experimentally. The dependences are similar within the temperature range 185-400 K. The scale of the curves obtained is shown to be proportional to a complex including the interaction potential parameters, ε2R03. The effect of the chemical surrounding of fluorine atoms on the response of the shielding electron-shell magnetic field to interaction with the surroundings can be characterized by parameter C specific of each particular probe molecule. The CCF4/CSF4 = 1.56 ratio is evaluated.",
author = "Terent'ev, {S. N.} and Zykov, {P. G.}",
year = "1996",
language = "English",
volume = "15",
pages = "1231--1236",
journal = "Chemical Physics Reports",
issn = "1074-1550",
publisher = "Cambridge International Science Publishing",
number = "8",

}

RIS

TY - JOUR

T1 - The effect of intermolecular interacations on magnetic shielding of nuclei of chemically bound atoms

AU - Terent'ev, S. N.

AU - Zykov, P. G.

PY - 1996

Y1 - 1996

N2 - Temperature dependences of the second virial coefficients of 19F magnetic shielding due to pair CF4-X, SF6-X, X-Xe, Kr, and CH4 interactions in gas phase are determined experimentally. The dependences are similar within the temperature range 185-400 K. The scale of the curves obtained is shown to be proportional to a complex including the interaction potential parameters, ε2R03. The effect of the chemical surrounding of fluorine atoms on the response of the shielding electron-shell magnetic field to interaction with the surroundings can be characterized by parameter C specific of each particular probe molecule. The CCF4/CSF4 = 1.56 ratio is evaluated.

AB - Temperature dependences of the second virial coefficients of 19F magnetic shielding due to pair CF4-X, SF6-X, X-Xe, Kr, and CH4 interactions in gas phase are determined experimentally. The dependences are similar within the temperature range 185-400 K. The scale of the curves obtained is shown to be proportional to a complex including the interaction potential parameters, ε2R03. The effect of the chemical surrounding of fluorine atoms on the response of the shielding electron-shell magnetic field to interaction with the surroundings can be characterized by parameter C specific of each particular probe molecule. The CCF4/CSF4 = 1.56 ratio is evaluated.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=10444225592

M3 - Article

VL - 15

SP - 1231

EP - 1236

JO - Chemical Physics Reports

JF - Chemical Physics Reports

SN - 1074-1550

IS - 8

ER -

ID: 54106168