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Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation. / Okhokhonin., Andrei; Stepanova, Marina; Tsmokaluk, Anton et al.
In: ChemistrySelect, Vol. 9, No. 10, e202304520, 2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Okhokhonin., A, Stepanova, M, Tsmokaluk, A, Mazur, A, Valieva, M, Starnovskaya, E, Gorbunov, E, Gaviko, V, Krinochkin, A, Kopchuk, D, Zyryanov, G, Kozitsina, A & Rusinov, V 2024, 'Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation', ChemistrySelect, vol. 9, no. 10, e202304520. https://doi.org/10.1002/slct.202304520

APA

Okhokhonin., A., Stepanova, M., Tsmokaluk, A., Mazur, A., Valieva, M., Starnovskaya, E., Gorbunov, E., Gaviko, V., Krinochkin, A., Kopchuk, D., Zyryanov, G., Kozitsina, A., & Rusinov, V. (2024). Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation. ChemistrySelect, 9(10), [e202304520]. https://doi.org/10.1002/slct.202304520

Vancouver

Okhokhonin. A, Stepanova M, Tsmokaluk A, Mazur A, Valieva M, Starnovskaya E et al. Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation. ChemistrySelect. 2024;9(10):e202304520. doi: 10.1002/slct.202304520

Author

Okhokhonin., Andrei ; Stepanova, Marina ; Tsmokaluk, Anton et al. / Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation. In: ChemistrySelect. 2024 ; Vol. 9, No. 10.

BibTeX

@article{86d10cfed9474dd88ebf98e5946cd4d7,
title = "Synthesis of (3‐Thienyl)‐Substituted 2,2{\textquoteright}‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation",
abstract = "Several new derivatives of 2,2′-bipyridines with a spacer group separated from the 2,2-bipyridine fragment, namely, an ethynyl fragment, were obtained using the Sonagashira cross-coupling reaction. The resulting derivatives were physically adsorbed on platinum electrode and were then used as activators of the catalytic activity of a platinum electrode in the reaction of cholesterol electrooxidation in an acetonitrile medium. Sensitivity, limit of detection and detectable concentration range were calculated, and the best results was established as 6.2±0.6 μA/mM, 0.08 mM and 0–0.3 mM, respectively. These results show that the prepared compounds adsorbed on platinum electrode are perspective systems for developing of new enzymeless cholesterol sensor based on them. {\textcopyright} 2024 Wiley-VCH GmbH.",
author = "Andrei Okhokhonin. and Marina Stepanova and Anton Tsmokaluk and Alena Mazur and Maria Valieva and Ekaterina Starnovskaya and Evgeny Gorbunov and Vasiliy Gaviko and Alexey Krinochkin and Dmitry Kopchuk and Grigory Zyryanov and Alisa Kozitsina and Vladimir Rusinov",
note = "This work was supported by the Russian Science Foundation [grant number 20‐13‐00142].",
year = "2024",
doi = "10.1002/slct.202304520",
language = "English",
volume = "9",
journal = "ChemistrySelect",
issn = "2365-6549",
publisher = "Wiley-Blackwell",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation

AU - Okhokhonin., Andrei

AU - Stepanova, Marina

AU - Tsmokaluk, Anton

AU - Mazur, Alena

AU - Valieva, Maria

AU - Starnovskaya, Ekaterina

AU - Gorbunov, Evgeny

AU - Gaviko, Vasiliy

AU - Krinochkin, Alexey

AU - Kopchuk, Dmitry

AU - Zyryanov, Grigory

AU - Kozitsina, Alisa

AU - Rusinov, Vladimir

N1 - This work was supported by the Russian Science Foundation [grant number 20‐13‐00142].

PY - 2024

Y1 - 2024

N2 - Several new derivatives of 2,2′-bipyridines with a spacer group separated from the 2,2-bipyridine fragment, namely, an ethynyl fragment, were obtained using the Sonagashira cross-coupling reaction. The resulting derivatives were physically adsorbed on platinum electrode and were then used as activators of the catalytic activity of a platinum electrode in the reaction of cholesterol electrooxidation in an acetonitrile medium. Sensitivity, limit of detection and detectable concentration range were calculated, and the best results was established as 6.2±0.6 μA/mM, 0.08 mM and 0–0.3 mM, respectively. These results show that the prepared compounds adsorbed on platinum electrode are perspective systems for developing of new enzymeless cholesterol sensor based on them. © 2024 Wiley-VCH GmbH.

AB - Several new derivatives of 2,2′-bipyridines with a spacer group separated from the 2,2-bipyridine fragment, namely, an ethynyl fragment, were obtained using the Sonagashira cross-coupling reaction. The resulting derivatives were physically adsorbed on platinum electrode and were then used as activators of the catalytic activity of a platinum electrode in the reaction of cholesterol electrooxidation in an acetonitrile medium. Sensitivity, limit of detection and detectable concentration range were calculated, and the best results was established as 6.2±0.6 μA/mM, 0.08 mM and 0–0.3 mM, respectively. These results show that the prepared compounds adsorbed on platinum electrode are perspective systems for developing of new enzymeless cholesterol sensor based on them. © 2024 Wiley-VCH GmbH.

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U2 - 10.1002/slct.202304520

DO - 10.1002/slct.202304520

M3 - Article

VL - 9

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 10

M1 - e202304520

ER -

ID: 54328698