Studying the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series for the sensitization of lanthanide(III) cations

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Studying the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series for the sensitization of lanthanide(III) cations. / Majee, Adinath; Krinochkin, Alexey P.; Valieva, Maria I. et al.
In: Journal of the Iranian Chemical Society, Vol. 21, No. 3, 01.03.2024, p. 731-740.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{406b3a871fb84ec5a7390ed39e84d0b9,

title = "Studying the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series for the sensitization of lanthanide(III) cations",

abstract = "A systematic study of the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series was carried out in terms of sensitization of lanthanide(III) cations. For this purpose, the corresponding DTTA-appended 5-aryl-2,2′-bipyridines were synthesized in good yields by using the “1,2,4-triazine” methodology, and their europium(III) and terbium(III) complexes were prepared. The photophysical properties were studied for all the obtained chelates, and the influence of the nature of the aryl substituent of the bipyridine core was estimated. The positive influence of the halogen atoms as well as a methyl group on the efficiency of the lanthanide(III) cation sensibilization was demonstrated. The influence of the nature of the residue of the polyaminocarboxylic acid fragment in the ligand on the luminescent characteristics of its lanthanide complexes was also studied. Graphical Abstract: (Figure presented.).",

author = "Adinath Majee and Krinochkin, {Alexey P.} and Valieva, {Maria I.} and Starnovskaya, {Ekaterina S.} and Shtaitz, {Yaroslav K.} and Kopchuk, {Dmitry S.} and Sougata Santra and Yuanli Liu and Zyryanov, {Grigory V.} and Chupakhin, {Oleg N.}",

note = "This work was supported by the Ministry of Science and Higher Education of the Russian Federation (Agreement #075-15-2022-1118 dated 29.06.2022).",

year = "2024",

month = mar,

day = "1",

doi = "10.1007/s13738-023-02954-z",

language = "English",

volume = "21",

pages = "731--740",

journal = "Journal of the Iranian Chemical Society",

issn = "1735-207X",

publisher = "Springer",

number = "3",

}

RIS

TY - JOUR

T1 - Studying the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series for the sensitization of lanthanide(III) cations

AU - Majee, Adinath

AU - Krinochkin, Alexey P.

AU - Valieva, Maria I.

AU - Starnovskaya, Ekaterina S.

AU - Shtaitz, Yaroslav K.

AU - Kopchuk, Dmitry S.

AU - Santra, Sougata

AU - Liu, Yuanli

AU - Zyryanov, Grigory V.

AU - Chupakhin, Oleg N.

N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation (Agreement #075-15-2022-1118 dated 29.06.2022).

PY - 2024/3/1

Y1 - 2024/3/1

N2 - A systematic study of the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series was carried out in terms of sensitization of lanthanide(III) cations. For this purpose, the corresponding DTTA-appended 5-aryl-2,2′-bipyridines were synthesized in good yields by using the “1,2,4-triazine” methodology, and their europium(III) and terbium(III) complexes were prepared. The photophysical properties were studied for all the obtained chelates, and the influence of the nature of the aryl substituent of the bipyridine core was estimated. The positive influence of the halogen atoms as well as a methyl group on the efficiency of the lanthanide(III) cation sensibilization was demonstrated. The influence of the nature of the residue of the polyaminocarboxylic acid fragment in the ligand on the luminescent characteristics of its lanthanide complexes was also studied. Graphical Abstract: (Figure presented.).

AB - A systematic study of the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series was carried out in terms of sensitization of lanthanide(III) cations. For this purpose, the corresponding DTTA-appended 5-aryl-2,2′-bipyridines were synthesized in good yields by using the “1,2,4-triazine” methodology, and their europium(III) and terbium(III) complexes were prepared. The photophysical properties were studied for all the obtained chelates, and the influence of the nature of the aryl substituent of the bipyridine core was estimated. The positive influence of the halogen atoms as well as a methyl group on the efficiency of the lanthanide(III) cation sensibilization was demonstrated. The influence of the nature of the residue of the polyaminocarboxylic acid fragment in the ligand on the luminescent characteristics of its lanthanide complexes was also studied. Graphical Abstract: (Figure presented.).

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85181443449

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001136878600001

U2 - 10.1007/s13738-023-02954-z

DO - 10.1007/s13738-023-02954-z

M3 - Article

VL - 21

SP - 731

EP - 740

JO - Journal of the Iranian Chemical Society

JF - Journal of the Iranian Chemical Society

SN - 1735-207X

IS - 3

ER -

ID: 54321428