The electroabsorption spectra within the range of nickel donor excitons in the semiconductors ZnSe:Ni and ZnO:Ni are presented. The defect vibrations in a crystal of ZnSe:Ni induced by Ni impurity ions having a charge state of + 1 with respect to the lattice are described. The calculations have been carried out in the framework of a recursive scheme in a shell model. Model calculations have enabled an interpretation of the vibronic structure in the electroabsorption spectra of Ni donor excitons in crystals of ZnSe:Ni and ZnO:Ni. The most intense vibrational replicas of the Ni donor exciton zero-phonon line appears to have a combination character ωII + nωI.
Original languageEnglish
Pages (from-to)1679-1683
Number of pages5
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume54
Issue number11
DOIs
Publication statusPublished - 1 Sept 1998

    ASJC Scopus subject areas

  • Instrumentation
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics
  • Analytical Chemistry

ID: 54651809