TY - JOUR

T1 - Preparation of multicomponent rare earth based oxide charges

AU - Ruseikina, Anna V.

AU - Grigoriev, Maxim V.

AU - Safin, Damir A.

PY - 2024

Y1 - 2024

N2 - In this study we describe a relatively facile synthetic approach for the production of multicomponent oxide charges as the precursors of quaternary barium-rare earth-copper selenides BaRECuSe3, which, in turn, are of interest as promising thermoelectric materials. The starting reagents were initially prepared, including cleaning of the surface of elemental copper and annealing the rare earth oxides RE2O3 in a high-temperature furnace. A mixture of double, ternary and quaternary oxide charges was prepared by dissolving the stoichiometric ratios of the starting reagents RE2O3:2Cu:2Ba(NO3)2 (RE = La, Nd, Gd, Dy, Ho, Y, Er, Tm, Yb, Lu), CeO2:Cu:Ba(NO3)2, Pr6O11:6Cu:6Ba(NO3)2 or Tb4O7:4Cu:4Ba(NO3)2 in nitric acid. The Ce-based oxide charge was obtained in the presence of H2O2 as a reducing agent to improve solubility in nitric acid. Then, cocrystallization of crystalline hydrates, followed by their dehydration, and destruction of the resulting (oxo)nitrate salts, and dispersion of the final polycrystalline samples were performed. According to the powder X-ray diffraction data, topochemical reactions led to the formation of heterometallic oxides BaxREyCuzOn, BaREO3, BaCuO2 and RE2CuO4. The developed synthetic approach allows to obtain the target phase of orthorhombic selenides BaRECuSe3 of three structural types BaLaCuS3, Eu2CuS3 and KZrCuS3 with high yields in a relatively short period of time and at lower temperatures in comparison to the previously used synthetic methods. © 2024 Elsevier B.V.

AB - In this study we describe a relatively facile synthetic approach for the production of multicomponent oxide charges as the precursors of quaternary barium-rare earth-copper selenides BaRECuSe3, which, in turn, are of interest as promising thermoelectric materials. The starting reagents were initially prepared, including cleaning of the surface of elemental copper and annealing the rare earth oxides RE2O3 in a high-temperature furnace. A mixture of double, ternary and quaternary oxide charges was prepared by dissolving the stoichiometric ratios of the starting reagents RE2O3:2Cu:2Ba(NO3)2 (RE = La, Nd, Gd, Dy, Ho, Y, Er, Tm, Yb, Lu), CeO2:Cu:Ba(NO3)2, Pr6O11:6Cu:6Ba(NO3)2 or Tb4O7:4Cu:4Ba(NO3)2 in nitric acid. The Ce-based oxide charge was obtained in the presence of H2O2 as a reducing agent to improve solubility in nitric acid. Then, cocrystallization of crystalline hydrates, followed by their dehydration, and destruction of the resulting (oxo)nitrate salts, and dispersion of the final polycrystalline samples were performed. According to the powder X-ray diffraction data, topochemical reactions led to the formation of heterometallic oxides BaxREyCuzOn, BaREO3, BaCuO2 and RE2CuO4. The developed synthetic approach allows to obtain the target phase of orthorhombic selenides BaRECuSe3 of three structural types BaLaCuS3, Eu2CuS3 and KZrCuS3 with high yields in a relatively short period of time and at lower temperatures in comparison to the previously used synthetic methods. © 2024 Elsevier B.V.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85188821576

U2 - 10.1016/j.inoche.2024.112281

DO - 10.1016/j.inoche.2024.112281

M3 - Article

VL - 163

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

SN - 1387-7003

M1 - 112281

ER -