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Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium. / Vazhenin, V. A.; Potapov, A. P.; Artyomov, M. Yu. et al.
In: Physics of the Solid State, Vol. 63, No. 5, 05.2021, p. 764-769.

Research output: Contribution to journal › Article › peer-review

Harvard

Vazhenin, VA, Potapov, AP, Artyomov, MY & Fokin, AV 2021, 'Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium', Physics of the Solid State, vol. 63, no. 5, pp. 764-769. https://doi.org/10.1134/S106378342105019X

APA

Vazhenin, V. A., Potapov, A. P., Artyomov, M. Y., & Fokin, A. V. (2021). Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium. Physics of the Solid State, 63(5), 764-769. https://doi.org/10.1134/S106378342105019X

Vancouver

Vazhenin VA, Potapov AP, Artyomov MY, Fokin AV. Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium. Physics of the Solid State. 2021 May;63(5):764-769. doi: 10.1134/S106378342105019X

Author

Vazhenin, V. A. ; Potapov, A. P. ; Artyomov, M. Yu. et al. / Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium. In: Physics of the Solid State. 2021 ; Vol. 63, No. 5. pp. 764-769.

BibTeX

@article{8424a85953b546bc9baaf6f298d97e32,
title = "Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium",
abstract = "Abstract: EPR spectra of impurity ions of Mn2+ (S = 5/2), Gd3+ (S = 7/2), and Cu2+ (S = 1/2) were found and investigated in addition to the intensive signals of axial centers of Cr4+ in the Li2CaSiO4 crystal. Manganese and gadolinium ions show spectra of tetragonal symmetry; copper ions show both spectra of axial and triclinic symmetry. Parameters of the spin Hamiltonians for the tetragonal centers were determined. Ions of Mn2+ and Gd3+ were shown to replace calcium ions with octahedral oxygen environment; copper ions are localized on lithium positions having tetrahedral environment. The reasons for appearing of triclinic Cu2+ centers are discussed.",
author = "Vazhenin, {V. A.} and Potapov, {A. P.} and Artyomov, {M. Yu.} and Fokin, {A. V.}",
year = "2021",
month = may,
doi = "10.1134/S106378342105019X",
language = "English",
volume = "63",
pages = "764--769",
journal = "Physics of the Solid State",
issn = "1063-7834",
publisher = "American Institute of Physics Publising LLC",
number = "5",

}

RIS

TY - JOUR

T1 - Paramagnetic Centers of Mn2+, Gd3+, and Cu2+ in Single Crystal of Li2CaSiO4 Doped with Chromium

AU - Vazhenin, V. A.

AU - Potapov, A. P.

AU - Artyomov, M. Yu.

AU - Fokin, A. V.

PY - 2021/5

Y1 - 2021/5

N2 - Abstract: EPR spectra of impurity ions of Mn2+ (S = 5/2), Gd3+ (S = 7/2), and Cu2+ (S = 1/2) were found and investigated in addition to the intensive signals of axial centers of Cr4+ in the Li2CaSiO4 crystal. Manganese and gadolinium ions show spectra of tetragonal symmetry; copper ions show both spectra of axial and triclinic symmetry. Parameters of the spin Hamiltonians for the tetragonal centers were determined. Ions of Mn2+ and Gd3+ were shown to replace calcium ions with octahedral oxygen environment; copper ions are localized on lithium positions having tetrahedral environment. The reasons for appearing of triclinic Cu2+ centers are discussed.

AB - Abstract: EPR spectra of impurity ions of Mn2+ (S = 5/2), Gd3+ (S = 7/2), and Cu2+ (S = 1/2) were found and investigated in addition to the intensive signals of axial centers of Cr4+ in the Li2CaSiO4 crystal. Manganese and gadolinium ions show spectra of tetragonal symmetry; copper ions show both spectra of axial and triclinic symmetry. Parameters of the spin Hamiltonians for the tetragonal centers were determined. Ions of Mn2+ and Gd3+ were shown to replace calcium ions with octahedral oxygen environment; copper ions are localized on lithium positions having tetrahedral environment. The reasons for appearing of triclinic Cu2+ centers are discussed.

UR - https://www.elibrary.ru/item.asp?id=47548773

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U2 - 10.1134/S106378342105019X

DO - 10.1134/S106378342105019X

M3 - Article

VL - 63

SP - 764

EP - 769

JO - Physics of the Solid State

JF - Physics of the Solid State

SN - 1063-7834

IS - 5

ER -

ID: 29488921