Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Novel Synthesis of Dihydrothiophene-2,5-diimine Derivatives by the Three-Component Reaction of Isocyanides with Enamines and Arylisothiocyanates
AU - A. mironov, Maxim
AU - N. ivantsova, Maria
AU - I. tokareva, Maria
AU - S. mokrushin, Vladimir
PY - 2007/1/1
Y1 - 2007/1/1
N2 - Abstract - A distribution of the products in the reaction of aryl isothiocyanates with isocyanides and 2,2-dialkylenamines has been studied in details. In range 55-60 C this reaction results in the formation of dihydrothiophene-2,5-diimine derivatives, constitutions of which are proved by an X-ray analysis. In contrast at high temperature (above 110 C) the major products in the present reaction are 2-imino-5-thiopyrrolidones. A one step pathway to dihydrothiophene structure has been elaborated.
AB - Abstract - A distribution of the products in the reaction of aryl isothiocyanates with isocyanides and 2,2-dialkylenamines has been studied in details. In range 55-60 C this reaction results in the formation of dihydrothiophene-2,5-diimine derivatives, constitutions of which are proved by an X-ray analysis. In contrast at high temperature (above 110 C) the major products in the present reaction are 2-imino-5-thiopyrrolidones. A one step pathway to dihydrothiophene structure has been elaborated.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=45349086573
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000253154500044
U2 - 10.3987/COM-07-S(U)33
DO - 10.3987/COM-07-S(U)33
M3 - Article
VL - 73
SP - 567
EP - 579
JO - Heterocycles
JF - Heterocycles
SN - 0385-5414
IS - 1
ER -
ID: 42249049