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Mechanosynthesis of Polyureas and Studies of Their Responses to Anions. / Al-Ithawi, Wahab K. A.; Aluru, Rammohan; Baklykov, Artem V. et al.
In: Polymers, Vol. 15, No. 20, 4160, 2023.

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@article{59e1a77034804f28865d3bb28cd820bd,
title = "Mechanosynthesis of Polyureas and Studies of Their Responses to Anions",
abstract = "Polyureas (PUs) have already found wide practical applications, and various methods of their synthesis have been reported. In this manuscript, we wished to report the very first mechanochemical approach towards aromatic PUs via reactions between isomeric 2,2′-, 3,3′-, and 4,4′-diaminobiphenyls and triphosgene under solvent-free conditions following ball-milling. By using this synthetic approach, both PUs and azomethine-capped Pus were obtained. The fluorescence response of the above-mentioned PUs towards various anions in solutions were studied and selective fluorescence responses towards the hydroxyl and fluoride anions were observed.",
author = "Al-Ithawi, {Wahab K. A.} and Rammohan Aluru and Baklykov, {Artem V.} and Khasanov, {Albert F.} and Kovalev, {Igor S.} and Nikonov, {Igor l.} and Kopchuk, {Dmitry S.} and Novikov, {Alexander S.} and Sougata Santra and Zyryanov, {Grigory V.} and Ranu, {Brindaban C.}",
note = "This research was funded by the Council for Grants of the President of the Russian Federation, Grant # NSh-1223.2022.1.3 (Mechanosynthesis of polyureas 7 –9), Ministry of Science and Higher Education of the Russian Federation, Reference # 075-15-2022-1118, dated 29 June 2022.",
year = "2023",
doi = "10.3390/polym15204160",
language = "English",
volume = "15",
journal = "Polymers",
issn = "2073-4360",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "20",

}

RIS

TY - JOUR

T1 - Mechanosynthesis of Polyureas and Studies of Their Responses to Anions

AU - Al-Ithawi, Wahab K. A.

AU - Aluru, Rammohan

AU - Baklykov, Artem V.

AU - Khasanov, Albert F.

AU - Kovalev, Igor S.

AU - Nikonov, Igor l.

AU - Kopchuk, Dmitry S.

AU - Novikov, Alexander S.

AU - Santra, Sougata

AU - Zyryanov, Grigory V.

AU - Ranu, Brindaban C.

N1 - This research was funded by the Council for Grants of the President of the Russian Federation, Grant # NSh-1223.2022.1.3 (Mechanosynthesis of polyureas 7 –9), Ministry of Science and Higher Education of the Russian Federation, Reference # 075-15-2022-1118, dated 29 June 2022.

PY - 2023

Y1 - 2023

N2 - Polyureas (PUs) have already found wide practical applications, and various methods of their synthesis have been reported. In this manuscript, we wished to report the very first mechanochemical approach towards aromatic PUs via reactions between isomeric 2,2′-, 3,3′-, and 4,4′-diaminobiphenyls and triphosgene under solvent-free conditions following ball-milling. By using this synthetic approach, both PUs and azomethine-capped Pus were obtained. The fluorescence response of the above-mentioned PUs towards various anions in solutions were studied and selective fluorescence responses towards the hydroxyl and fluoride anions were observed.

AB - Polyureas (PUs) have already found wide practical applications, and various methods of their synthesis have been reported. In this manuscript, we wished to report the very first mechanochemical approach towards aromatic PUs via reactions between isomeric 2,2′-, 3,3′-, and 4,4′-diaminobiphenyls and triphosgene under solvent-free conditions following ball-milling. By using this synthetic approach, both PUs and azomethine-capped Pus were obtained. The fluorescence response of the above-mentioned PUs towards various anions in solutions were studied and selective fluorescence responses towards the hydroxyl and fluoride anions were observed.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85175316689

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001089531100001

U2 - 10.3390/polym15204160

DO - 10.3390/polym15204160

M3 - Article

VL - 15

JO - Polymers

JF - Polymers

SN - 2073-4360

IS - 20

M1 - 4160

ER -

ID: 47872384