Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Low-temperature helium defectoscopy and interaction of helium with ions of cerium gadolinium ceramics Ce0.8Gd0.2O1.9 with a submicrocrystalline structure
AU - Kupryazhkin, A. Ya.
AU - Kovalenko, M. A.
AU - Koromyslov, A. V.
AU - Zhiganov, A. N.
PY - 2011/6/1
Y1 - 2011/6/1
N2 - The concentration of unbound neutral anion vacancies in cerium gadolinium ceramics Ce(0.8)Gd(0.2)O(1.9) with a submicrocrystalline structure has been determined using low-temperature helium defectoscopy at temperatures ranging from 613 to 773 K and at saturation pressures from 0.05 to 12 MPa. It has been found that the energy of dissociation of impurity-vacancy complexes is 1.1 +/- 0.2 eV, and the energy of dissolution of helium in defects is -0.8 +/- 0.2 eV. The obtained results have been compared both with the experimental data on the energy of interaction between helium and ions of the cerium gadolinium ceramics and with the results of the quantum-chemical calculations. It has been demonstrated that the anomalously low value of the energy of helium dissolution in the studied ceramic samples is determined by the chemical interaction of helium with the nearest environment of the cerium cations.
AB - The concentration of unbound neutral anion vacancies in cerium gadolinium ceramics Ce(0.8)Gd(0.2)O(1.9) with a submicrocrystalline structure has been determined using low-temperature helium defectoscopy at temperatures ranging from 613 to 773 K and at saturation pressures from 0.05 to 12 MPa. It has been found that the energy of dissociation of impurity-vacancy complexes is 1.1 +/- 0.2 eV, and the energy of dissolution of helium in defects is -0.8 +/- 0.2 eV. The obtained results have been compared both with the experimental data on the energy of interaction between helium and ions of the cerium gadolinium ceramics and with the results of the quantum-chemical calculations. It has been demonstrated that the anomalously low value of the energy of helium dissolution in the studied ceramic samples is determined by the chemical interaction of helium with the nearest environment of the cerium cations.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000292557900017
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=79958744738
U2 - 10.1134/S1063783411060175
DO - 10.1134/S1063783411060175
M3 - Article
VL - 53
SP - 1198
EP - 1201
JO - Physics of the Solid State
JF - Physics of the Solid State
SN - 1063-7834
IS - 6
ER -
ID: 37848629