Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Grain boundary self-diffusion of tracer 18O atoms in nanocrystalline oxide LaMnO3 + δ
AU - Vykhodets, V. B.
AU - Vykhodets, E. V.
AU - Gizhevskii, B. A.
AU - Zakharov, Robert G.
AU - Kozlov, E. A.
AU - Kurennykh, T. E.
AU - Petrova, S. A.
AU - Trakhtenberg, I. Sh.
AU - Fishman, Anatolii Ya.
N1 - This work was supported by the Russian Foundation for Basic Research (project nos. 06-03-72003-MNTI and 06-03-32943) and the Federal Agency for Science and Innovations (contract no. 02.513.11.3142).
PY - 2008/3/1
Y1 - 2008/3/1
N2 - Diffusion coefficients of tracer 18O atoms at boundaries of nanograins of LaMnO3 + δ oxide have been measured in the temperature range of 400–500°C. The samples of the nanocrystalline oxide are prepared with the use of the shockwave loading method. The concentration profile of the tracer atoms after diffusion annealing is measured with the use of the nuclear microanalysis method. The activation energies of the grain boundary diffusion amounts to about 2 eV and the boundary width is ∼0.05 nm. The measured coefficients of the grain boundary diffusion at 500°C exceed the corresponding coefficients of the volume diffusion by seven orders of magnitude.
AB - Diffusion coefficients of tracer 18O atoms at boundaries of nanograins of LaMnO3 + δ oxide have been measured in the temperature range of 400–500°C. The samples of the nanocrystalline oxide are prepared with the use of the shockwave loading method. The concentration profile of the tracer atoms after diffusion annealing is measured with the use of the nuclear microanalysis method. The activation energies of the grain boundary diffusion amounts to about 2 eV and the boundary width is ∼0.05 nm. The measured coefficients of the grain boundary diffusion at 500°C exceed the corresponding coefficients of the volume diffusion by seven orders of magnitude.
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000254656300011
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=41749110444
U2 - 10.1134/S0021364008020112
DO - 10.1134/S0021364008020112
M3 - Article
VL - 87
SP - 115
EP - 119
JO - JETP Letters
JF - JETP Letters
SN - 0021-3640
IS - 2
ER -
ID: 38900065