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First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In. / Vykhodets, Vladimir; Nefedova, Olga; Kurennykh, Tatiana et al.
In: Metals, Vol. 13, No. 2, 394, 02.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Vykhodets, V, Nefedova, O, Kurennykh, T & Vykhodets, E 2023, 'First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In', Metals, vol. 13, no. 2, 394. https://doi.org/10.3390/met13020394

APA

Vykhodets, V., Nefedova, O., Kurennykh, T., & Vykhodets, E. (2023). First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In. Metals, 13(2), [394]. https://doi.org/10.3390/met13020394

Vancouver

Vykhodets V, Nefedova O, Kurennykh T, Vykhodets E. First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In. Metals. 2023 Feb;13(2):394. doi: 10.3390/met13020394

Author

Vykhodets, Vladimir ; Nefedova, Olga ; Kurennykh, Tatiana et al. / First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In. In: Metals. 2023 ; Vol. 13, No. 2.

BibTeX

@article{265d137f1eaf4d559549720524aa8e89,
title = "First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In",
abstract = "Diffusion of deuterium in indium is studied herein. In the temperature range 200–350 K, mass transfer is controlled predominantly by the mechanism of overbarrier atomic jumps; at temperatures from 80 to 120 K, by tunneling; whereas in the range from 120 to 200 K, there takes place a gradual transition from one migration mechanism to the other. These results are of fundamental significance since it is shown for the first time that quantum diffusion can be observed in a metal with a crystal lattice other than the body centered cubic one. Conditions are specified that are necessary for the observation of quantum diffusion of hydrogen: low values of Debye temperature, density of atomic packing in the lattice, and distance between the nearest equilibrium positions of hydrogen atoms. Moreover, data on the influence of point defects on hydrogen tunneling in solids are gained for the first time as well. The quantum diffusion coefficient is twice as high in the sample with enhanced vacancy concentration.",
author = "Vladimir Vykhodets and Olga Nefedova and Tatiana Kurennykh and Evgenia Vykhodets",
note = "The research was carried out within the state assignment of Ministry of Science and Higher Education of the Russian Federation (theme “Function” No. АААА-А19-119012990095-0).",
year = "2023",
month = feb,
doi = "10.3390/met13020394",
language = "English",
volume = "13",
journal = "Metals",
issn = "2075-4701",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "2",

}

RIS

TY - JOUR

T1 - First Observation of Quantum Diffusion in Non-Cubic Metal: Deuterium Diffusion in In

AU - Vykhodets, Vladimir

AU - Nefedova, Olga

AU - Kurennykh, Tatiana

AU - Vykhodets, Evgenia

N1 - The research was carried out within the state assignment of Ministry of Science and Higher Education of the Russian Federation (theme “Function” No. АААА-А19-119012990095-0).

PY - 2023/2

Y1 - 2023/2

N2 - Diffusion of deuterium in indium is studied herein. In the temperature range 200–350 K, mass transfer is controlled predominantly by the mechanism of overbarrier atomic jumps; at temperatures from 80 to 120 K, by tunneling; whereas in the range from 120 to 200 K, there takes place a gradual transition from one migration mechanism to the other. These results are of fundamental significance since it is shown for the first time that quantum diffusion can be observed in a metal with a crystal lattice other than the body centered cubic one. Conditions are specified that are necessary for the observation of quantum diffusion of hydrogen: low values of Debye temperature, density of atomic packing in the lattice, and distance between the nearest equilibrium positions of hydrogen atoms. Moreover, data on the influence of point defects on hydrogen tunneling in solids are gained for the first time as well. The quantum diffusion coefficient is twice as high in the sample with enhanced vacancy concentration.

AB - Diffusion of deuterium in indium is studied herein. In the temperature range 200–350 K, mass transfer is controlled predominantly by the mechanism of overbarrier atomic jumps; at temperatures from 80 to 120 K, by tunneling; whereas in the range from 120 to 200 K, there takes place a gradual transition from one migration mechanism to the other. These results are of fundamental significance since it is shown for the first time that quantum diffusion can be observed in a metal with a crystal lattice other than the body centered cubic one. Conditions are specified that are necessary for the observation of quantum diffusion of hydrogen: low values of Debye temperature, density of atomic packing in the lattice, and distance between the nearest equilibrium positions of hydrogen atoms. Moreover, data on the influence of point defects on hydrogen tunneling in solids are gained for the first time as well. The quantum diffusion coefficient is twice as high in the sample with enhanced vacancy concentration.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85149240264

U2 - 10.3390/met13020394

DO - 10.3390/met13020394

M3 - Article

VL - 13

JO - Metals

JF - Metals

SN - 2075-4701

IS - 2

M1 - 394

ER -

ID: 36090290