Research output: Contribution to journal › Article › peer-review
Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Fast ionic transport in solid polymer electrolytes based on acrylonitrile copolymers
AU - Bushkova, O. V.
AU - Zhukovsky, V. M.
AU - Lirova, B. I.
AU - Kruglyashov, A. L.
N1 - This work was financially supported by the Russian Fundamental Research Foundation (grant No 97-03-32347) and the Russian Ministry of Education (grant No 97-9.3-324).
PY - 1999/4/1
Y1 - 1999/4/1
N2 - Conducting properties of solid polymer electrolytes (SPEs) based on acrylonitrile copolymer (with 93 wt.% acrylonitrile units) and LiClO4 have been studied by a complex impedance and potentiostatic techniques. The results indicate existence of a highly ionically-conductive concentration region close to the limit of salt solubility. The formation of an ionic structure favourable for fast Li-ion transport is governed mainly by the following factors: absence of residual low molecular weight solvent (illustrated by conductivity and lithium transport numbers measurements) and temperature (IR spectroscopy investigations) influence.
AB - Conducting properties of solid polymer electrolytes (SPEs) based on acrylonitrile copolymer (with 93 wt.% acrylonitrile units) and LiClO4 have been studied by a complex impedance and potentiostatic techniques. The results indicate existence of a highly ionically-conductive concentration region close to the limit of salt solubility. The formation of an ionic structure favourable for fast Li-ion transport is governed mainly by the following factors: absence of residual low molecular weight solvent (illustrated by conductivity and lithium transport numbers measurements) and temperature (IR spectroscopy investigations) influence.
UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=0032653545
UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=000079859900034
U2 - 10.1016/S0167-2738(98)00506-2
DO - 10.1016/S0167-2738(98)00506-2
M3 - Article
VL - 119
SP - 217
EP - 222
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
IS - 1-4
ER -
ID: 53414035