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Co(II), Cu(II), and Mn(II) complexes based on 2,2’-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species. / Moseev, Timofey D.; Nikiforov, Egor A.; Varaksin, Mikhail V. et al.
In: Inorganica Chimica Acta, Vol. 558, 121727, 01.12.2023.

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@article{fb9f1b1b071544ed98c6091ac72fa5ac,
title = "Co(II), Cu(II), and Mn(II) complexes based on 2,2{\textquoteright}-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species",
abstract = "A series of new Co(II), Cu(II), and Mn(II) complexes containing both aromatic and aliphatic organofluorine species were obtained in 76–90% yields. Structural properties of these coordination compounds derived from pentafluorophenyl-substituted 3-(2-pyridyl)-1,2,4-triazine, 2,2′-bipyridine and hexafluoroacetylacetonate ligands were comprehensively studied using by XRD analysis, with the slightly distorted octahedral coordination being revealed in all cases. The spatial characteristics for 3-(2-pyridyl)-1,2,4-triazine bearing pentafluorophenyl moiety at C(5) position as well as its bipyridine analog in relation to ones for the corresponding metal complexes were also studied. The revealed structural features for the elaborated Co(II), Cu(II), and Mn(II) complexes based on 2,2′-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species could be of particular interest in the design of advanced materials for catalysis, chemosensory, molecular electronics, and other fields of materials science.",
author = "Moseev, {Timofey D.} and Nikiforov, {Egor A.} and Varaksin, {Mikhail V.} and Valieva, {Maria I.} and Kopchuk, {Dmitry S.} and Litvinov, {Igor A.} and Gaviko, {Vasiliy S.} and Slepukhin, {Pavel A.} and Zyryanov, {Grigory V.} and Charushin, {Valery N.} and Chupakhin, {Oleg N.}",
note = "The research was financially supported by the Russian Science Foundation (RSF) according to the research project № 20-73-10077, https://rscf.ru/en/project/20-73-10077/.",
year = "2023",
month = dec,
day = "1",
doi = "10.1016/j.ica.2023.121727",
language = "English",
volume = "558",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",

}

RIS

TY - JOUR

T1 - Co(II), Cu(II), and Mn(II) complexes based on 2,2’-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species

AU - Moseev, Timofey D.

AU - Nikiforov, Egor A.

AU - Varaksin, Mikhail V.

AU - Valieva, Maria I.

AU - Kopchuk, Dmitry S.

AU - Litvinov, Igor A.

AU - Gaviko, Vasiliy S.

AU - Slepukhin, Pavel A.

AU - Zyryanov, Grigory V.

AU - Charushin, Valery N.

AU - Chupakhin, Oleg N.

N1 - The research was financially supported by the Russian Science Foundation (RSF) according to the research project № 20-73-10077, https://rscf.ru/en/project/20-73-10077/.

PY - 2023/12/1

Y1 - 2023/12/1

N2 - A series of new Co(II), Cu(II), and Mn(II) complexes containing both aromatic and aliphatic organofluorine species were obtained in 76–90% yields. Structural properties of these coordination compounds derived from pentafluorophenyl-substituted 3-(2-pyridyl)-1,2,4-triazine, 2,2′-bipyridine and hexafluoroacetylacetonate ligands were comprehensively studied using by XRD analysis, with the slightly distorted octahedral coordination being revealed in all cases. The spatial characteristics for 3-(2-pyridyl)-1,2,4-triazine bearing pentafluorophenyl moiety at C(5) position as well as its bipyridine analog in relation to ones for the corresponding metal complexes were also studied. The revealed structural features for the elaborated Co(II), Cu(II), and Mn(II) complexes based on 2,2′-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species could be of particular interest in the design of advanced materials for catalysis, chemosensory, molecular electronics, and other fields of materials science.

AB - A series of new Co(II), Cu(II), and Mn(II) complexes containing both aromatic and aliphatic organofluorine species were obtained in 76–90% yields. Structural properties of these coordination compounds derived from pentafluorophenyl-substituted 3-(2-pyridyl)-1,2,4-triazine, 2,2′-bipyridine and hexafluoroacetylacetonate ligands were comprehensively studied using by XRD analysis, with the slightly distorted octahedral coordination being revealed in all cases. The spatial characteristics for 3-(2-pyridyl)-1,2,4-triazine bearing pentafluorophenyl moiety at C(5) position as well as its bipyridine analog in relation to ones for the corresponding metal complexes were also studied. The revealed structural features for the elaborated Co(II), Cu(II), and Mn(II) complexes based on 2,2′-bipyridine and 3-(2-pyridyl)-1,2,4-triazine ligands containing organofluorine species could be of particular interest in the design of advanced materials for catalysis, chemosensory, molecular electronics, and other fields of materials science.

UR - http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=85169884488

UR - https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=tsmetrics&SrcApp=tsm_test&DestApp=WOS_CPL&DestLinkType=FullRecord&KeyUT=001162811100001

U2 - 10.1016/j.ica.2023.121727

DO - 10.1016/j.ica.2023.121727

M3 - Article

VL - 558

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 121727

ER -

ID: 44646844