A systematic study of phase equilibria of the Y2O3 – BaO – Fe2O3 system in the vicinity of YBa2Fe3O8+δ reveals that the actual composition of the 123-type oxide differs from the ideal one. It is shown that a single-phase oxide with a 123-type structure can be obtained at 1373 ​K in air only with a slight deficit of Ba and an excess of both Y and Fe components. The overall formula of the single-phase 123-type oxide is written as Y1.05Ba1.92Fe3.03O8+δ. The composition of one more complex oxide, which is absent in the reported earlier phase diagram, is also found to be Ba-deficient; it can be presented as Y1.04Ba0.96FeO4. As a result, the revised version of phase diagram for the Y2O3 – BaO – Fe2O3 system is constructed at 1373 ​K in air.
Original languageEnglish
Article number123992
JournalJournal of Solid State Chemistry
Volume322
DOIs
Publication statusPublished - 1 Jun 2023

    WoS ResearchAreas Categories

  • Chemistry, Inorganic & Nuclear
  • Chemistry, Physical

    ASJC Scopus subject areas

  • Materials Chemistry
  • Condensed Matter Physics
  • Inorganic Chemistry
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Physical and Theoretical Chemistry

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