Abstract: A phenomenological model describing the change in the structural characteristics of loose zinc deposits obtained in pulsed current modes is presented. Comparison of experimental data on the structural properties of deposits with the results of model calculations indicates the adequacy of the model. To describe the features of the dendritic deposit growth and to determine the duration of the homogeneous structure formation in pulsed modes, the concept of critical thickness is introduced, at which a sharp change in the loose deposit density occurs. The dependence of the zinc deposit critical thickness on the pulse duty ratio under pulsed current modes is determined. The increasing of the pulse duty ratio leads to denser deposits with rounded dendrite shapes and fewer growth points, as compared with the deposit obtained in galvanostatic mode. © 2023, Pleiades Publishing, Ltd.
Original languageEnglish
Pages (from-to)501-511
Number of pages11
JournalRussian Journal of Electrochemistry
Volume59
Issue number7
DOIs
Publication statusPublished - 2023

    WoS ResearchAreas Categories

  • Electrochemistry

    ASJC Scopus subject areas

  • Electrochemistry

ID: 43261702