The processes of strontium hexaferrite (permanent magnet material) fabrication in combustion reactions followed by heat treatment of organic nitrate precursors containing glycine or polyvinyl alcohol have been studied. The formation of iron-glycine complexes of organic precursor components affects the formation of the morphology of the obtained samples. When using glycine-containing systems during combustion, a branched fibrous texture of the material with extended internal cavities with elongated oxide particles emerges. Such samples have a higher coercivity; the external magnetic field has no significant influence on the texture formation during combustion. It was established that charges are generated in precursors during their combustion, which manifests itself in the appearance of a potential difference between the ground and the precursor. In this case, the appearance of lower intensity charges allows us to obtain samples with higher magnetization, as well as with a greater ability to increase the magnetic characteristics during further thermomagnetic processing.