The study covers kinetic features of gold cementation from cyanide solutions using two zinc powders of various origins. The first one was obtained by distillation and is currently applied in gold cementation from cyanide solutions (traditional powder). The second one was obtained by electrochemical reduction from the alkaline solution (experimental, electrolytic powder). The main distinguishing feature of these cementation powders is their specific surface area. This indicator for the electrolytic powder is2.6 times higher than for the traditional one (3.02 m2/g and 1.16 m2/g, respectively) due to its dendritic form. The studies used a solution with a gold content of 50.8 μmol/dm3 and a sodium cyanide content of 0.04 mol/dm3 NaCN was taken. Cementation revealed a powder depassivation period associated with oxide film dissolution and overcoming diffusion difficulties. The traditional powder depassivation period (10-15 sec) exceeds that of the electrolytic powder (5-8 sec). Experimental rate constants of the cementation reaction were determined for the process involving both powders under study at different ratios of zinc and gold masses in the solution. Experimental reaction rate constants for the electrolytic powder under the studied conditions were 1.3-1.6 times higher than that for the traditional powder. It was found that oxidation rates of zinc powders compared at different ratios of zinc and gold masses are virtually the same. At the same time, absolute rates of electrolytic powder dissolution in the initialperiod are nearly 2 times greater. As the powder reacts with the alkaline solution, absolute dissolution rates of electrolytic and traditional powders are equalized.